The joint is a grid, not a second tile.
Each tile sits in a module of tile length plus joint width, by tile width plus joint width. Tiles per square foot are 144 divided by that module area. Grout per tile, in cubic inches, is joint width times joint depth times the length of the two joints and the corner once: tile length plus tile width plus joint width. Cubic feet are those cubic inches times tiles per square foot times the area, divided by 1,728. Pounds are cubic feet times the pounds per cubic foot you enter. One hundred is a starting density so the example has a number. Match the bag if it publishes a density or a coverage chart. The grout coverage calculator you trust is that chart. This geometry is the estimate before the chart corrects it.